Read Ebook: Scientific American Supplement No. 441 June 14 1884. by Various

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The Electro-Chemical Equivalent of Silver

A New Process for Making Wrought Iron Directly from the Ore. --Comparison with other processes.--With descriptions and engravings of the apparatus used

Some Remarks on the Determination of Hardness in Water

The Pantanemone.--A New Windwheel.--1 engraving

Relvas's New Life Boat.--With engraving

Experiments with Double Barreled Guns and Rifles. --Cause of the divergence of the charge.--4 figures

Improved Ball Turning Machine.--1 figure

Cooling Apparatus for Injection Water.--With engraving

Corrugated Disk Pulleys.--1 engraving

Density and Pressure of Detonating Gas

The Kravogl Electro Motor and its Conversion Into a Dynamo Electric Machine.--5 figures

Bornhardt's Electric Machine for Blasting in Mines. --15 figures

Pritchett's Electric Fire Alarm.--1 figure

A Standard Thermopile

Telephonic Transmission without Receivers.--Some of the apparatus exhibited at the annual meeting of the French Society of Physics.--Telephonic transmission through a chain of persons

Drinkstone Park.--Trees and plants cultivated therein.-- With 2 engravings

FAURE'S MACHINE FOR DECORTICATING SUGAR-CANE.

The object of the apparatus shown in the accompanying engraving is to effect a separation of the tough epidermis of the sugar-cane from the internal spongy pith which is to be pressed. Its function consists in isolating and separating the cells from their cortex, and in putting them in direct contact with the rollers or cylinders of the mill. After their passage into the apparatus, which is naturally placed in a line with the endless chain that carries them to the mill, the canes arrive in less compact layers, pass through much narrower spaces, and finally undergo a more efficient pressure, which is shown by an abundant flow of juice. The first trials of the machine were made in 1879 at the Pointe Simon Works, at Martinique, with the small type that was shown at the Paris Exhibition of 1878. These experiments, which were applied to a work of 3,000 kilos of cane per hour, gave entire satisfaction, and decided the owners of three of the colonial works to adopt it for the season of 1880.

The apparatus is shown in longitudinal section in Fig. 1, and in plan in Fig. 2.

Fig. 3 gives a transverse section passing through the line 3-4, and Fig. 4 an external view on the side whence the decorticated canes make their exit from the apparatus.

The other figures relate to details that will be referred to further along.

The exit plates, D', are provided with 7 spiral channels of the same pitch and direction as those of the preceding, but the depth of which increases from 2 to 10 mm. The axis of the decorticating cylinder does not coincide with that of the vessel, B', so that the free interval for the passage of the cane continues to diminish from the entrance to the exit.

If we allow that the motor has a velocity of 70 revolutions per minute, the decorticating cylinder will run at the rate of 50, and the sugar-cane will move forward at the rate of 12 meters per minute.

This new machine is a very simple and powerful one. The decortication is effected with wonderful rapidity, and the canes, opened throughout their entire length and at all points of their circumference, leave the apparatus in a state that allows of no doubt as to what the result of the pressure will be that they have to undergo. There is no tearing, no trituration, no loss of juice, but merely a simple preparation for a rational pressure effected under most favorable conditions.

MOVING A BRIDGE.

An interesting piece of engineering work has recently been accomplished at Bristol, England, which consisted in the moving of a foot-bridge 134 feet in length, bodily, down the river a considerable distance. The pontoons by means of which the bridge was floated to its new position consisted of four 80-ton barges, braced together so as to form one solid structure 64 feet in width, and were placed in position soon after the tide commenced to rise. At six o'clock A.M. the top of the stages, which was 24 feet above the water, touched the under part of the bridge, and in a quarter of an hour later both ends rose from their foundations. When the tide had risen 4 ft. the stage and bridge were floated to the new position, when at 8.30 the girders dropped on to their beds.

THE GENERATION OF STEAM, AND THE THERMODYNAMIC PROBLEMS INVOLVED.

It will not be necessary to commence this lecture by explaining the origin of fuel; it will be sufficient if I remind you that it is to the action of the complex rays of the sun upon the foliage of plants that we mainly owe our supply of combustibles. The tree trunks and branches of our forests, as well as the subterranean deposits of coal and naphtha, at one time formed portions of the atmosphere in the form of carbonic acid gas; that gas was decomposed by the energy of the solar rays, the carbon and the oxygen were placed in positions of advantage with respect to each other--endowed with potential energy; and it is my duty this evening to show how we can best make use of these relations, and by once more combining the constituents of fuel with the oxygen of the air, reverse the action which caused the growth of the plants, that is to say, by destroying the plant reproduce the heat and light which fostered it. The energy which can be set free by this process cannot be greater than that derived originally from the sun, and which, acting through the frail mechanism of green leaves, tore asunder the strong bonds of chemical affinity wherein the carbon and oxygen were hound, converting the former into the ligneous portions of the plants and setting the latter free for other uses. The power thus silently exerted is enormous; for every ton of carbon separated in twelve hours necessitates an expenditure of energy represented by at least 1,058 horse power, but the action is spread over an enormous area of leaf surface, rendered necessary by the small proportion of carbonic acid contained in the air, by measure only 1/2000 part, and hence the action is silent and imperceptible. It is now conceded on all hands that what is termed heat is the energy of molecular motion, and that this motion is convertible into various kinds and obeys the general laws relating to motion. Two substances brought within the range of chemical affinity unite with more or less violence; the motion of transition of the particles is transformed, wholly or in part, into a vibratory or rotary motion, either of the particles themselves or the interatomic ether; and according to the quality of the motions we are as a rule, besides other effects, made conscious of heat or light, or of both. When these emanations come to be examined they are found to be complex in the extreme, intimately bound up together, and yet capable of being separated and analyzed.

As soon as the law of definite chemical combination was firmly established, the circumstance that changes of temperature accompanied most chemical combinations was noticed, and chemists were not long in suspecting that the amount of heat developed or absorbed by chemical reaction should be as much a property of the substances entering into combination as their atomic weights. Solid ground for this expectation lies in the dynamic theory of heat. A body of water at a given height is competent by its fall to produce a definite and invariable quantity of heat or work, and in the same way two substances falling together in chemical union acquire a definite amount of kinetic energy, which, if not expended in the work of molecular changes, may also by suitable arrangements be made to manifest a definite and invariable quantity of heat.

At the end of last century Lavoisier and Laplace, and after them, down to our own time, Dulong, Desprez, Favre and Silbermann, Andrews, Berthelot, Thomson, and others, devoted much time and labor to the experimental determination of the heat of combustion and the laws which governed its development. Messrs. Favre and Silbermann, in particular, between the years 1845 and 1852, carried out a splendid series of experiments by means of the apparatus partly represented in Fig. 1 , which is a drawing one-third the natural size of the calorimeter employed. It consisted essentially of a combustion chamber formed of thin copper, gilt internally. The upper part of the chamber was fitted with a cover through which the combustible could be introduced, with a pipe for a gas jet, with a peep hole closed by adiathermanous but transparent substances, alum and glass, and with a branch leading to a thin copper coil surrounding the lower part of the chamber and descending below it. The whole of this portion of the apparatus was plunged into a thin copper vessel, silvered internally and filled with water, which was kept thoroughly mixed by means of agitators. This second vessel stood inside a third one, the sides and bottom of which were covered with the skins of swans with the down on, and the whole was immersed in a fourth vessel tilled with water, kept at the average temperature of the laboratory. Suitable thermometers of great delicacy were provided, and all manner of precautions were taken to prevent loss of heat.

Comparison with later determinations have established their substantial accuracy. The general conclusion arrived at is thus stated:

"As a rule there is an equality between the heat disengaged or absorbed in the acts, respectively, of chemical combination or decomposition of the same elements, so that the heat evolved during the combination of two simple or com-pound substances is equal to the heat absorbed at the time of their chemical segregation."

Composition of air--

and water evaporated from and at 212?, taking 966 units as the heat necessary to evaporate 1 pound of water,

carbon, hydrogen, and oxygen being taken at their weight per cent. in the fuel. Strictly speaking, marsh gas should be separately determined. It often happens that available energy is not in a form in which it can be applied directly to our needs. The water flowing down from the mountains in the neighborhood of the Alpine tunnels was competent to provide the power necessary for boring through them, but it was not in a form in which it could be directly applied. The kinetic energy of the water had first to be changed into the potential energy of air under pressure, then, in that form, by suitable mechanism, it was used with signal success to disintegrate and excavate the hard rock of the tunnels. The energy resulting from combustion is also incapable of being directly transformed into useful motive power; it must first be converted into potential force of steam or air at high temperature and pressure, and then applied by means of suitable heat engines to produce the motions we require. It is probably to this circumstance that we must attribute the slowness of the human race to take advantage of the energy of combustion. The history of the steam engine hardly dates back 200 years, a very small fraction of the centuries during which man has existed, even since historic times.

The apparatus by means of which the potential energy of fuel with respect to oxygen is converted into the potential energy of steam, we call a steam boiler; and although it has neither cylinder nor piston, crank nor fly wheel, I claim for it that it is a veritable heat engine, because it transmits the undulations and vibrations caused by the energy of chemical combination in the fuel to the water in the boiler; these motions expend themselves in overcoming the liquid cohesion of the water and imparting to its molecules that vigor of motion which converts them into the molecules of a gas which, impinging on the surfaces which confine it and form the steam space, declare their presence and energy in the shape of pressure and temperature. A steam pumping engine, which furnishes water under high pressure to raise loads by means of hydraulic cranes, is not more truly a heat engine than a simple boiler, for the latter converts the latent energy of fuel into the latent energy of steam, just as the pumping engine converts the latent energy of steam into the latent energy of the pumped-up accumulator or the hoisted weight.

I will illustrate this important doctrine in the manner which Carnot himself suggested.

that is to say, the greatest amount of work which can be expected is found by multiplying the weight of water into the clear fall, which is, of course, self-evident.

Now, how can the quantity of work to be got out of a given weight of water be increased without in any way improving the efficiency of the turbine? In two ways:

that is to say, under the extremely favorable if not impracticable conditions assumed, there must be a loss of 11 per cent. Next, to give a numerical value to the potential energy, H, to be derived from a pound of carbon, calculating from absolute zero, the specific heat of carbon being 0.25, and absolute temperature of air 520?:

Equal to 16.69 lb. of water evaporated from and at 212?. Hence the greatest possible evaporation from and at 212? from a lb. of carbon--

The data necessary for our purpose are:

The temperature of the furnace not having been determined, we must calculate it on the supposition, which will be justified later on, that 50 per cent more air was admitted than was theoretically necessary to supply the oxygen required for perfect combustion. This would make 18 lb. of air per 1 lb. of coal; consequently 19 lb. of gases would be heated by 14,727 units of heat. Hence:

The specific heat of coal is very nearly that of gases at constant pressure, and may, without sensible error, be taken as such. The potential energy of 1 lb. of coal, therefore, with reference to the oxygen with which it will combine, and calculated from absolute zero, is:

Hence work to be expected from the boiler:

of water evaporated from and at 212?, corresponding to 12,819 units. The actual result obtained was 11.83 lb.; hence the efficiency of this boiler was

This last proposition indicates the defective information which Carnot possessed. He knew that expansion of the elastic agent was accompanied by a fall of temperature, but he did not know that that fall was due to the conversion of heat into work. We should state this clause more correctly by saying that "the cooling of the agent must be caused by the external work it performs." In accordance with these propositions, it is immaterial what the heated gases or vapors in the furnace of a boiler may be, provided that they cool by doing external work and, in passing over the boiler surfaces, impart their heat energy to the water. The temperature of the furnace, it follows, must be kept as high as possible. The process of combustion is usually complex. First, in the case of coal, close to the fire-bars complete combustion of the red hot carbon takes place, and the heat so developed distills the volatile hydrocarbons and moisture in the upper layers of the fuel. The inflammable gases ignite on or near the surface of the fuel, if there be a sufficient supply of air, and burn with a bright flame for a considerable distance around the boiler. If the layer of fuel be thin, the carbonic acid formed in the first instance passes through the fuel and mixes with the other gases. If, however, the layer of fuel be thick, and the supply of air through the bars insufficient, the carbonic acid is decomposed by the red hot coke, and twice the volume of carbonic oxide is produced, and this, making its way through the fuel, burns with a pale blue flame on the surface, the result, as far as evolution of heat is concerned, being the same as if the intermediate decomposition of carbonic acid had not taken place. This property of coal has been taken advantage of by the late Sir W. Siemens in his gas producer, where the supply of air is purposely limited, in order that neither the hydrocarbons separated by distillation, nor the carbonic oxide formed in the thick layer of fuel, may be consumed in the producer, but remain in the form of crude gas, to be utilized in his regenerative furnaces.

PLANETARY WHEEL-TRAINS.

This is, clearly, the motion of A relatively to the fixed frame of the machine; and is measured from a fixed vertical line through the center of A. Now, if we wish to express the total motion of F relatively to the same fixed frame, we must measure it from a vertical line through the center of F, wherever that maybe; which gives in this case:

but with respect to the train-arm when at rest, we have:

In this deduction of the formula, as in that of Prof. Rankine, all the motions are supposed to have the same direction, corresponding to that of the hands of the clock; and in its application to any given train, the signs of the terms must be changed in case of any contrary motion, as explained in the preceding article.

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